1561890-67-2Relevant articles and documents
An unprecedented Pd-catalyzed trans-addition of boronic acids to ynamides
Yang, Yuanfa,Wang, Lina,Zhang, Jieni,Jin, Yali,Zhu, Gangguo
supporting information, p. 2347 - 2349 (2014/03/21)
An unprecedented Pd-catalyzed trans-addition of boronic acids to ynamides has been reported, giving α,β-disubstituted enamides in high yields with excellent regio- and stereoselectivity. A possible mechanism involving the palladium carbene intermediate has been proposed to account for the unusual trans-addition. The Royal Society of Chemistry 2014.