1563187-43-8Relevant articles and documents
Enantioselective Michael addition of cyclic ketones to nitroolefins catalyzed by a novel fluorine-insertion organocatalyst
Wang, Yanan,Jiang, Min,Liu, Jin-Tao
, p. 212 - 218 (2014)
A novel fluorine-insertion organocatalyst, which was designed based on the fluorine-ammonium ion gauche effect, was synthesized and used successfully to catalyze the asymmetric Michael addition of cyclic ketones to nitroolefins. High yields and excellent diastereo- and enantioselectivities were achieved under mild conditions. A possible stereochemical model is also proposed.