156479-56-0Relevant articles and documents
Site-Selective Fluorination of Organic Compounds Using 1-Alkyl-4-fluoro-1,4-diazabicyclooctane Salts (Selectfluor Reagents)
Lal, G. Sankar
, p. 2791 - 2796 (1993)
The new "N-F"-type electrophilic reagent family of 1-alkyl-4-fluoro-1,4-diazabicyclooctane salts (derived from elemental fluorine (F2) and 1-alkyl-1,4-diazabicyclooctane salts) has been found to be very effective for the fluorination of a wide variety of organic substrates.These include steroidal enol acetates and silyl enol ethers, phenyl-substituted olefins, sulfides bearing α-H atoms, certain carbanions, and mildly activated aromatic compounds.The products were obtained with good yields and regioselectivity under very mild reaction conditions.
Isolation and characterization of methyl hypofluorite (CH3OF)
Kol, Moshe,Rozen, Shlomo,Appelman, Evan
, p. 2648 - 2651 (2007/10/02)
Methyl hypofluorite (CH3OF) has prepared by the reaction of elemental fluorine with methanol in acetonitrile or propionitrile at low temperature. It removed from the reaction mixture in a stream of nitrogen purified by fractional distillation.