156699-64-8

Basic information

• Product Name: 1-phenylsulphonyl-2-(tridecafluorohexyl)pyrrole
• Synonyms: 1-phenylsulphonyl-2-(tridecafluorohexyl)pyrrole
• CAS NO: 156699-64-8
• Molecular Weight: 525.29
• Mol File: 156699-64-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-phenylsulphonyl-2-(tridecafluorohexyl)pyrrole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylsulphonyl-2-(tridecafluorohexyl)pyrrole(156699-64-8)
• EPA Substance Registry System: 1-phenylsulphonyl-2-(tridecafluorohexyl)pyrrole(156699-64-8)

Safety Data

• Hazardous Substances Data: 156699-64-8(Hazardous Substances Data)

Upstream product

• 16851-82-4 N-phenylsulfonylpyrrole 
• 55591-23-6 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane-1-sulfonyl chloride 

Relevant articles and documents

A novel perfluoroalkylation of pyrroles with perfluoroalkanesulfonyl chloride catalyzed by a ruthenium(II) phosphine complex

Direct perfluoroalkylation of N-substituted pyrroles with tridecafluorohexanesulfonyl chloride catalyzed by a ruthenium(II) phosphine complex proceeds regioselectively in high yield.

Direct Perfluoroalkylation of Aromatic and Heteroaromatic Compounds with Perfluoroalkanesulfonyl Chlorides Catalysed by a Ruthenium(II) Phosphine Complex

The perfluoroalkylation of aromatic and heteroaromatic compounds by perfluoroalkanesulfonyl chlorides 1 has been investigated in the presence of a ruthenium(II) phosphine complex.The reaction of compounds 1 with substituted benzenes or thiophenes proceeded smoothly with extrusion of sulfur dioxide at 120 deg C to give corresponding perfluoroalkylated compounds in good yield.No expected perfluoroalkylated product was obtained in the reaction of compounds 1 with pyrrole; however, 1-trimethylsilyl- and 1-triisopropylsilyl-pyrrole were regioselectively perfluoroalkylated at their 2- and 3-position, respectively.