156817-47-9Relevant articles and documents
Asymmetric total synthesis of (R)-α-cuparenone, (S)-cuparene and formal synthesis of (R)-β-cuparenone through Meinwald rearrangement and ring closing metathesis (RCM) reaction
Kumar, Rajan,Halder, Joydev,Nanda, Samik
, p. 809 - 818 (2017/01/16)
Asymmetric synthesis of enantiopure cuparenoid sesquiterpenes (R)-α-cuparenone, (S)-cuparene and a formal synthesis of (R)-β-cuparenone was presented in this article. Meinwald rearrangement of an enantiopure trisubstituted 2,3-epoxy alcohol derivative was
Intramolecular Photocycloaddition of the C=C Double Bond to the CN Triple Bond Resulting in the Formation of a Novel Cyclic System
Sakuragi, Hirochika,Koyama, Toshiya,Sakurazawa, Mamoru,Yasui, Norimichi,Tokumaru, Katsumi,Ueno, Katsuhiko
, p. 1769 - 1772 (2007/10/02)
Irradiation of a bichromophoric 1-(o-cyanobenzyloxy)-2-(p-methoxyphenyl)-2-butene (1a) in cyclohexane gave an isoquinoline derivative, 8-methoxy-6-methyl-11,13-dihydrobenzoxepinoisoquinoline (2a). The structure was determined by X-ray analysis. The formation of 2a can be accounted for by the initial cycloaddition of 1a in the excited singlet state between the C=C double bond and CN triple bond, followed by cleavage of the resulting azetine ring and recyclization.
