1569075-99-5

Basic information

• Product Name: ethyl 2-{(1S,2R,5S,6S)-2-[(E)-6-iodo-3,3-dimethoxyhepta-1,6-dien-1-yl]-2,6-dimethyl-5-triisopropylsilyloxycyclohexyl}acetate
• Synonyms: ethyl 2-{(1S,2R,5S,6S)-2-[(E)-6-iodo-3,3-dimethoxyhepta-1,6-dien-1-yl]-2,6-dimethyl-5-triisopropylsilyloxycyclohexyl}acetate
• CAS NO: 1569075-99-5
• Molecular Weight: 650.754
• Mol File: 1569075-99-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 2-{(1S,2R,5S,6S)-2-[(E)-6-iodo-3,3-dimethoxyhepta-1,6-dien-1-yl]-2,6-dimethyl-5-triisopropylsilyloxycyclohexyl}acetate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-{(1S,2R,5S,6S)-2-[(E)-6-iodo-3,3-dimethoxyhepta-1,6-dien-1-yl]-2,6-dimethyl-5-triisopropylsilyloxycyclohexyl}acetate(1569075-99-5)
• EPA Substance Registry System: ethyl 2-{(1S,2R,5S,6S)-2-[(E)-6-iodo-3,3-dimethoxyhepta-1,6-dien-1-yl]-2,6-dimethyl-5-triisopropylsilyloxycyclohexyl}acetate(1569075-99-5)

Safety Data

• Hazardous Substances Data: 1569075-99-5(Hazardous Substances Data)

Upstream product

• 1549824-53-4 (1S,2S,3S,4S)-phenyl-2-(2-ethoxy-2-oxoethyl)-1,3-dimethyl-4-(triisopropylsilyloxy)cyclohexanecarboxylate 
• 1569075-95-1 ethyl 2-{(1S,2R,5S,6S)-2-[(E)-6-iodo-3-oxohepta-1,6-dien-1-yl]-2,6-dimethyl-5-triisopropylsilyloxycyclohexyl}acetate 
• 149-73-5 trimethyl orthoformate 
• 1569075-94-0 dimethyl (5-iodo-2-oxohex-5-en-1-yl)phosphonate 
• 1569075-93-9 ethyl 2-((1S,2S,5S,6S)-2-formyl-2,6-dimethyl-5-((triisopropylsilyl)oxy)cyclohexyl)acetate 

Downstream Products

• 1569076-00-1 C₂₈H₅₃IO₄Si 
• 1569076-02-3 2-{(1S,2R,5S,6S)-2-[(E)-6-iodo-3,3-dimethoxyhepta-1,6-dien-1-yl]-2,6-dimethyl-5-triisopropylsilyloxycyclohexyl}acetaldehyde 
• 1569076-05-6 (4aR,4bS,7S,8S,8aS,10aR)-4b,8-dimethyl-10a-phenylthiomethyl-7-triisopropylsilyloxydecahydrophenanthrene-3,10(2H,4H)-dione 
• 1569076-06-7 (4aS,4bS,7S,8S,8aS,10aS)-4b,8-dimethyl-10a-phenylthiomethyl-7-triisopropylsilyloxydecahydrophenanthrene-3,10(2H,4H)-dione 

Relevant articles and documents

Stereoselective construction of the ABC-ring system of fusidane triterpenes via intermolecular/transannular Michael reaction cascade

A stereoselective construction of the ABC-ring system of fusidane triterpenes via intermolecular/transannular Michael reaction cascade is described. The substrate, a ten-membered carbocyclic ketone, has been successfully prepared by the Cr-mediated intramolecular alkenylation of the corresponding acyclic compound. The array of functionalities in the product stereoselectively obtained by the cascade reaction is useful for further structural modifications directed toward the total synthesis of fusidane and other triterpenes, and designed molecules intended for studying structure-activity relationships.