157007-74-4Relevant articles and documents
Highly diastereoselective addition of photochemically generated radicals to (5R)-(-)-menthyloxy-2[5H]-furanone - Synthesis of (-)-terebic acid
Hoffmann
, p. 879 - 886 (1994)
Photochemically generated ketyl and 2-dioxolanyl radicals are added with high diastereoselectivity (de > 95%) to (5R)-(-)-5-menthyloxy-2[5H]-furanone. This reaction is used for the asymmetric synthesis of (-)-terebic acid. The double bond is attacked by t
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Sasaki et al.
, p. 3582,3584 (1969)
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KINETIC RESOLUTION OF RACEMIC β,γ-EPOXY ESTERS WITH PIG LIVER ESTERASE (PLE, E.C. 3.1.1.1.)
Mohr, Peter,Roesslein, Lukas,Tamm, Christoph
, p. 2513 - 2516 (2007/10/02)
The β,γ-epoxy esters (+/-)-2 to (+/-)-6 were synthetisized.The E-values of kinetic resolution of 2, 3, 4, and 6 with PLE and the absolute configuration of the products of the hydrolysis were determined by the conversion to known compounds.