157667-92-0Relevant articles and documents
Photoinduced electron transfer (PET) promoted cyclisations of 1-[N-alkyl-N-(trimethylsilyl)methyl]amines tethered to proximate olefin: Mechanistic and synthetic perspectives
Pandey, Ganesh,Devi Reddy,Kumaraswamy
, p. 8185 - 8194 (2007/10/02)
Upon PET reaction, amines of type 1 undergo efficient cyclisations to produce pyrrolidines and piperidines. Mechanistically, involvement of delocalised α-silylmethyl amine radical cation as reactive intermediate in such cyclisations are described.