157750-33-9

Basic information

• Product Name: [Co(III)(N-(dibutylcarbamothioyl)benzamide(-H))3]
• CAS NO: 157750-33-9
• Molecular Weight: 933.305
• Mol File: 157750-33-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Co(III)(N-(dibutylcarbamothioyl)benzamide(-H))3](CAS DataBase Reference)
• NIST Chemistry Reference: [Co(III)(N-(dibutylcarbamothioyl)benzamide(-H))3](157750-33-9)
• EPA Substance Registry System: [Co(III)(N-(dibutylcarbamothioyl)benzamide(-H))3](157750-33-9)

Safety Data

• Hazardous Substances Data: 157750-33-9(Hazardous Substances Data)

Upstream product

• 68141-55-9 N-benzoyl-N’,N’-(di-n-butyl)thiourea 

Relevant articles and documents

Tris-chelate complexes of cobalt(III) with N-[di(alkyl/aryl)carbamothioyl] benzamide derivatives: Synthesis, crystallography and catalytic activity in TBHP oxidation of alcohols

New six coordinated tris-chelate cobalt(III) complexes of the type [Co(L)3] (1-4) {where HL = N-[di(alkyl/aryl)carbamothioyl]benzamide derivatives}were prepared from the reaction between CoCl2· 6H2O and N-[di(alkyl/aryl)carbamothioyl]benzamide in ethanol and characterized by elemental analysis and spectral data (UV/Vis, IR, 1H & 13C NMR). The molecular structure of a representative complex [Co(L1)3] (1) [where HL1 = N-(diisopropylcarbamothioyl)benzamide], was determined by single crystal X-ray diffraction method and reveals a distorted octahedral geometry and a facial configuration of S atoms around the Co(III) center. These complexes act as efficient catalysts for the oxidation of alcohols to their corresponding aldehydes or ketones in presence of tert-butyl hydroperoxide (TBHP) at 80°C.