157758-63-9

Basic information

• Product Name: ethyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside
• Synonyms: ethyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside
• CAS NO: 157758-63-9
• Molecular Weight: 536.689
• Mol File: 157758-63-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ethyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside(157758-63-9)
• EPA Substance Registry System: ethyl 6-O-acetyl-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside(157758-63-9)

Safety Data

• Hazardous Substances Data: 157758-63-9(Hazardous Substances Data)

Upstream product

• 65556-30-1 1,6-di-O-acetyl-2,3,4-tri-O-benzyl-α-D-mannopyranoside 
• 75-08-1 ethanethiol 

Downstream Products

• 157758-66-2 octyl 3,4,6-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-6-O-diphenoxyphosphoryl-α-D-mannopyranosyl)-α-D-mannopyranoside 
• 157758-65-1 octyl 3,4,6-tri-O-benzyl-2-O-(2,3,4-tri-O-benzyl-α-D-mannopyranosyl)-α-D-mannopyranoside 
• 157758-68-4 octyl 2-O-α-D-mannopyranosyl-α-D-mannopyranoside 
• 543698-60-8 ethyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 543698-61-9 ethyl O-(3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-(1->6)-2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 39483-51-7 ethyl 2,3,4-tri-O-benzyl-1-thio-α-D-mannopyranoside 
• 157758-64-0 octyl 2-O-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-mannopyranosyl)-3,4,6-tri-O-benzyl-α-D-mannopyranoside 

Relevant articles and documents

Synthesis of octyl 2-O-α-D-mannopyranosyl-α-D-mannopyranoside, its 6'-phosphate and the corresponding monomethyl phosphodiester: intermediate structures in the biosynthesis of N-linked oligosaccharides in Dictyostelium discoidium

Octyl 2-O-α-D-mannopyranosyl-α-D-mannopyranoside, its 6'-phosphate and the corresponding 6'-methyl phosphodiester have been chemically synthesized.The latter compound was prepared using an H-phosphonate intermediate.These structures are for use as enzyme substrates and reference standards in a study on the biosynthesis of phosphorylated N-linked glycoproteins in the amoebae Dictyostelium discoideum.

Peptide templated glycosylation reactions

Glycosyl donors and acceptors may be covalently linked to aspartic acid residues via OH-6 esters. Peptide elaboration allows glycosylation reactions to be performed between donors and acceptors linked to this peptide template. These reactions display increased regio- and stereoselectivities, which are dependent on the nature of the peptide. Simple molecular modelling is used to rationalise the differing product distributions obtained by variation of the linking amino acid sequence. Copyright (C) 2000 Elsevier Science Ltd.