157869-10-8

Basic information

• Product Name: Benzenamine, 2-(1-octynyl)-
• CAS NO: 157869-10-8
• Molecular Formula: C14H19N
• Molecular Weight: 201.312
• Mol File: 157869-10-8.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzenamine, 2-(1-octynyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 2-(1-octynyl)-(157869-10-8)
• EPA Substance Registry System: Benzenamine, 2-(1-octynyl)-(157869-10-8)

Safety Data

• Hazardous Substances Data: 157869-10-8(Hazardous Substances Data)

Upstream product

• 629-05-0 n-octyne 
• 615-43-0 2-iodophenylamine 

Downstream Products

• 215997-62-9 N-mesyl-2-(oct-1-ynyl)aniline 
• 92499-12-2 2-hexyl-1H-indole 
• 1200659-91-1 1-(2-aminophenyl)-1-octanone 
• 37413-50-6 2-octylaniline 
• 1427513-97-0 4-bromo-1-iodo-2-octylbenzene 
• 851511-96-1 VPC₂₃₀₈₇ 
• 448960-04-1 C₃₀H₅₃N₂O₇P 
• 448960-02-9 C₂₂H₃₆N₂O₄ 
• 449173-23-3 VPC₂₃₀₈₉ 
• 502157-83-7 1-iodo-2-(oct-1-yn-1-yl)benzene 
• 1558818-26-0 C₂₃H₂₆O₂ 
• 1476035-16-1 1-(2-hexyl-1H-indol-3-yl)-2-phenylethane-1,2-dione 
• 1213786-10-7 2-hexyl-3-(phenylthio)-1H-indole 
• 448960-00-7 C₂₉H₃₈N₂O₄ 

Relevant articles and documents

Palladium-Catalyzed Oxidation-Hydroxylation and Oxidation-Methoxylation of N -Boc Indoles for the Synthesis of 3-Oxoindolines

The palladium-catalyzed oxidation-hydroxylation and oxidation-methoxylation of N -Boc indoles for the synthesis of tert -butyl 2-hydroxy(methoxy)-3-oxoindoline-1-carboxylates and their derivatives is developed. The process occurs readily using PdCl 2 as the catalyst and acetonitrile as the solvent to afford 3-oxoindolines in moderate to high yields. A mechanism for this Pd-catalyzed oxidation-hydroxylation and oxidation-methoxylation of N -Boc indoles is proposed.

CuI-Catalyzed intramolecular aminocyanation of terminal alkynes in N-(2-ethynylphenyl)-N-sulfonylcyanamides via Cu-vinylidene intermediates

CuI-Catalyzed intramolecular aminocyanation of terminal alkynes in N-(2-ethynylphenyl)-N-sulfonylcyanamides was initiated by the formation of Cu-acetylide to trigger N-CN bond cleavage of the N-sulfonylcyanamide moiety followed by CN migration to form a β-cyano Cu-vinylidene intermediate. Subsequently, the indole ring closure furnished the corresponding 1-sulfonyl-3-cyanoindoles.

Palladium-catalyzed intermolecular aerobic oxidative cyclization of 2-ethynylanilines with isocyanides: Regioselective synthesis of 4-halo-2-aminoquinolines

A robust and regioselective palladium-catalyzed intermolecular aerobic oxidative cyclization of 2-ethynylanilines with isocyanides to the synthesis of 4-halo-2-aminoquinolines is reported herein. The procedure constructs various 4-halo-2-aminoquinolines w