158197-45-6

Basic information

• Product Name: Benzenemethanol, a-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]butyl]-, (S)-
• CAS NO: 158197-45-6
• Molecular Formula: C17H30O2Si
• Molecular Weight: 294.51
• Mol File: 158197-45-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, a-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]butyl]-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, a-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]butyl]-, (S)-(158197-45-6)
• EPA Substance Registry System: Benzenemethanol, a-[4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]butyl]-, (S)-(158197-45-6)

Safety Data

• Hazardous Substances Data: 158197-45-6(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 108794-10-1 4-[(tert-butyldimethylsilyl)oxy]-1-butene 
• 85807-84-7 tert-butyl(5-hexenyloxy)dimethylsilane 

Relevant articles and documents

Catalytic Asymmetric Reductive Addition of Olefins to Aldehydes Mediated by Boron and Zinc Organometallics

A procedure involving a hydroboration, boron-zinc exchange and asymmetric addition to an aldehyde allows the reductive addition of olefins to aldehydes in 50-96percent ee.A short and efficient 3 step synthesis of ginnol (61percent overall yield, 92percent ee) demonstrates the synthetic utility of the method.