158309-73-0Relevant articles and documents
Reactions of thioesters of phosphorus acids with cationic complexes of manganese
Sinyashin, Oleg,Milyukov, Vasily,Zverev, Alexandr,Plyamovatyi, Alexandr,Mukhamadeeva, Raviya,Batyeva, Elvira,Ginzburg, Allan,Sokolov, Vyacheslav
, p. 137 - 140 (1996)
The thioesters of P(III) acids react with [Cp(CO)2Mn(NO)]+ by substituting one CO-group with formation of a stable cationic products with a Mn-P bond. Fourier transform infrared spectroscopy and a special program were used for the real-time monitoring of the mechanistic path of the reaction of S-ethyl-N,N-tetraethyldiamidothiophosphite with [Cp(CO)2Mn(NO)]- BF4+. The formation of a few intermediates is described.