15842-03-2Relevant articles and documents
Direct Oxidative Addition-Reductive Elimination Reactions Between trans- and or trans- (M = Rh or Ir, L = tertiary phosphine)
Al-Jibori, Subhi,Crocker, Christopher,Shaw, Bernard L.
, p. 319 - 321 (2007/10/02)
Complexes of the type trans- and .M = Rh or Ir, L = PMe2Ph or PEt2Ph, have been shown to react with each other, presumably by a double chloro-bridged intermediate, and undergo rapid oxidative addition-reductive elimination; phosphine exchange is much slower.Similar results were obtained when trans- was treated with trans-, M = Rh or Ir, for which rapid and complete conversion into trans- and occured. (31)P NMR data are given.