1585185-79-0

Basic information

• Product Name: C₁₉H₁₈INO₂S
• Synonyms: C₁₉H₁₈INO₂S
• CAS NO: 1585185-79-0
• Molecular Weight: 451.328
• Mol File: 1585185-79-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₉H₁₈INO₂S(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₉H₁₈INO₂S(1585185-79-0)
• EPA Substance Registry System: C₁₉H₁₈INO₂S(1585185-79-0)

Safety Data

• Hazardous Substances Data: 1585185-79-0(Hazardous Substances Data)

Upstream product

• 55022-46-3 4-methyl-N-prop-2-ynylbenzenesulfonamide 
• 108-86-1 bromobenzene 
• 1585185-86-9 C₁₉H₁₈INO₂S 
• 70396-10-0 (Z)-3-iodo-2-phenyl-prop-2-en-1-ol 

Downstream Products

• 1585185-65-4 C₂₀H₂₁NO₃S 
• 10477-94-8 3-methyl-5-phenylpyridine 
• 1585185-75-6 C₂₂H₂₅NO₄S 
• 1585185-71-2 C₂₁H₂₃NO₃S 
• 1585185-72-3 C₂₂H₂₅NO₃S 

Relevant articles and documents

An organocatalytic method for constructing pyrroles: Via the cycloisomerisation of Z -1-iodo-4- N -methylbenzenesulfonyl-1,6-enynes

A new cycloisomerisation of Z-1-iodo-4-N-methylbenzenesulfonyl-1,6-enynes to functionalized pyrroles was realized in the presence of an organomolecule (4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine) and KOtBu. The transformations were performed efficiently to produce different kinds of functionalized pyrroles within 10 min. This is the first example of an organomolecule promoted methodology with vinyl iodides from a non-aromatic system to an aromatic system, which offers an excellent option toward establishing a new horizon for cross-coupling reactions of vinyl halides. Preliminary mechanistic studies were performed and a crude radical pathway was proposed.