158566-96-2Relevant articles and documents
Reactions of LiCHR2 and related lithium alkyls with a-H free nitriles and the crystal structures of eleven representative lithium 1,3-diazaallyls, 1-azaallyls and β-diketiminates
Hitchcock, Peter B.,Laeppert, Michael F.,Layh, Marcus,Liu, Dian-Sheng,Sablong, Rafael,Shun, Tian
, p. 2301 - 2312 (2000)
Reactions between bis(trimethylsilyl)methyllithium LiCHR2 and a nitrile R'CN gave lithium 1-azaallyls, β-diketiminates or 1,3-diazaallyls. The products of related processes involving the lithium alkyl LiCH2R, LiCH(R)Ph or [Li(tmen)]2[l,2-{C(H)R}2C6H4] hav