158833-25-1

Basic information

• Product Name: naphthalen-1-ylmethyl phenyl carbonate
• Synonyms: naphthalen-1-ylmethyl phenyl carbonate
• CAS NO: 158833-25-1
• Molecular Weight: 278.307
• Mol File: 158833-25-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: naphthalen-1-ylmethyl phenyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: naphthalen-1-ylmethyl phenyl carbonate(158833-25-1)
• EPA Substance Registry System: naphthalen-1-ylmethyl phenyl carbonate(158833-25-1)

Safety Data

• Hazardous Substances Data: 158833-25-1(Hazardous Substances Data)

Upstream product

• 4780-79-4 1-naphthalene methanol 
• 1885-14-9 phenyl chloroformate 

Downstream Products

• 1003-66-3 phenol-d1 
• 28942-32-7 4-(naphthalen-1-ylmethyl)phenol 
• 28942-31-6 2-(naphthalen-1-ylmethyl)phenol 
• 6245-96-1 α-naphthylmethyl phenyl ether 
• 5903-23-1 1-(methoxymethyl)naphthalene 
• 108-95-2 phenol 

Relevant articles and documents

Palladium-Catalyzed Decarboxylative Carbonylative Transformation of Benzyl Aryl Carbonates: Direct Synthesis of Aryl 2-Arylacetates

A procedure on palladium-catalyzed decarboxylative alkoxycarbonylation of carbonates for the synthesis of aryl 2-arylacetates has been developed. A broad range of aryl 2-arylacetates were obtained in good yields under mild conditions under a carbon monoxide atmosphere. Interestingly, other alcohols can be added as nucleophiles as well, and the corresponding esters were also obtained in good yields.

Photochemistry of 1-naphthylmethyl carbonates and carbamates

The photochemistry in methanol of 1-naphthylmethyl phenyl carbonate (3) and 1-naphthylmethyl benzyl carbonate (4) has been studied. Products resulting from both the 1-naphthylmethyl cation and the 1-naphthylmethyl radical are obtained for 3, but only from