158923-11-6 Usage
Description
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE is a complex organic compound with a unique chemical structure. It is an orange powder and is sold in collaboration with Solvias AG. (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE is characterized by its chemical properties and potential applications in various industries.
Uses
1. Used in Chemical Synthesis:
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE is used as a ligand in the palladium-catalyzed hetero cross-coupling between aryl bromides/aryl triflates with potassium thioacetate to form S-aryl thioacetates. This application is particularly relevant in the field of organic chemistry, where the compound plays a crucial role in facilitating specific chemical reactions and synthesizing target molecules.
2. Used in Pharmaceutical Industry:
In the pharmaceutical industry, (R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE may be utilized as a key intermediate or building block in the development of new drugs or drug candidates. Its unique chemical structure and properties make it a valuable asset in the design and synthesis of novel therapeutic agents.
3. Used in Material Science:
The compound may also find applications in material science, where it could be used to develop new materials with specific properties or to improve the performance of existing materials. Its unique structure and chemical properties could contribute to the creation of advanced materials with applications in various industries, such as electronics, aerospace, or automotive.
4. Used in Research and Development:
(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE can be employed in research and development settings to explore its potential applications and properties further. Scientists and researchers may use this compound to investigate new chemical reactions, study its interactions with other molecules, or develop new methods for its synthesis and purification.
Reaction
Ligand for Palladium-catalyzed C-N cross-coupling.
Ligand for Palladium-catalyzed C-S cross-coupling.
Ligand for Palladium-catalyzed Kumada couplings of aryl and vinyl tosylates.
Ligand for Rhodium-catalyzed hydroacylation of cyclopropenes, an enatioselective desymmetrization method.
Ligand for Palladium-catalyzed C-O cross-coupling.
Ligand for Rhodium-catalyzed coupling of imidazole derivatives with terminal allenes.
Ligand for Ruthenium-catalyzed C-C coupling of alkynes and alcohols to form branched products of carbonyl allylation
Check Digit Verification of cas no
The CAS Registry Mumber 158923-11-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,8,9,2 and 3 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 158923-11:
(8*1)+(7*5)+(6*8)+(5*9)+(4*2)+(3*3)+(2*1)+(1*1)=156
156 % 10 = 6
So 158923-11-6 is a valid CAS Registry Number.
InChI:InChI=1/C27H47P2.C5H5.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h14,19-23H,8-13,15-18H2,1-7H3;1-5H;/t21-;;/m0../s1
158923-11-6Relevant articles and documents
Synthesis of ferrocenyl diphosphine ligands: Substitution of α-methoxy or α-dimethylamino groups by phosphines. Retention versus inversion: A stereochemical study
Schuecker, Raffael,Weissensteiner, Walter,Mereiter, Kurt,Lotz, Matthias,Spindler, Felix
, p. 6443 - 6458 (2010)
The stereochemical course of the exchange reaction of α-methoxy or α-dimethylamino groups by phosphines in acetic acid has been studied for ferrocene derivatives that have either a ferrocenylethyl or a benzylferrocenyl backbone. The reaction proceeded with either retention or inversion of configuration depending on the substrate stereoisomer used. The parameters that influence the stereochemical course of these reactions, such as relative configuration or substitution patterns, are discussed.
