1589553-85-4Relevant articles and documents
Non-symmetric 9,10-diphenylanthracene-based deep-blue emitters with enhanced charge transport properties
Serevicius, Tomas,Komskis, Regimantas,Adomenas, Povilas,Adomeniene, Ona,Jankauskas, Vygintas,Gruodis, Alytis,Kazlauskas, Karolis,Jursenas, Saulius
, p. 7089 - 7101 (2014/04/03)
Realization of efficient deep-blue anthracene-based emitters with superior film-forming and charge transport properties is challenging. A series of non-symmetric 9,10-diphenylanthracenes (DPA) with phenyl and pentyl moieties at the 2nd position and alkyl groups at para positions of the 9,10-phenyls were synthesized and investigated. The non-symmetric substitution at the 2nd position enabled to improve film forming properties as compared to those of the unsubstituted DPA and resulted in glass transition temperatures of up to 92 °C. Small-sized and poorly conjugated substituents allowed to preserve emission in the deep blue range (-3-1 × 10 -2 cm2 V-1 s-1) in the solution-processed amorphous films of the DPA compounds.