159189-61-4

Basic information

• Product Name: 1-methyl>-3,5-di-t-butylbenzene
• Synonyms: 1-methyl>-3,5-di-t-butylbenzene
• CAS NO: 159189-61-4
• Molecular Weight: 590.847
• Mol File: 159189-61-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-methyl>-3,5-di-t-butylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl>-3,5-di-t-butylbenzene(159189-61-4)
• EPA Substance Registry System: 1-methyl>-3,5-di-t-butylbenzene(159189-61-4)

Safety Data

• Hazardous Substances Data: 159189-61-4(Hazardous Substances Data)

Upstream product

• 17610-00-3 3,5-Di-tert-butylbenzaldehyde 
• 97336-41-9 ethyl 3,4-diethyl-1H-pyrrole-2-carboxylate 

Downstream Products

• 159189-63-6 1--3,5-di-t-butylbenzene 
• 159189-62-5 1--3,5-di-t-butylbenzene 

Relevant articles and documents

Intramolecular ligation of carbonyl oxygen to central zinc in synthetic oligopeptide-linked zinc-porphyrins

Oligopeptide-linked zinc-porphyrins were prepared (oligopeptide = -Phe(m)-Ala(n)-OMe and porphyrin = 5,15-diaryl-2,3,7,8,12,13,17,18-octaethylporphyrin). 1H NMR, IR, visible, and CD spectra of the synthetic molecule in a chlorinated methane (CDCl3 or CH2Cl2) showed that the carbonyl oxygen of the N-terminal amino acid of the linked peptide should ligate the central zine metal in the molecule as the axial ligand to form a pentacoordinated zinc-porphyrin. The coordination of the zinc with the peptide framework changed the optical and electrical properties, indicating that such ligation might control the reactivity in biological metallotetrapyrrole-protein systems as well as the coordination to the peptide residue.