1592-72-9Relevant articles and documents
Fast (hetero)aryl-benzothiazolium ethenes photoswitches activated by visible-light at room temperature
Coelho, Paulo J.,Castro, M. Cidália R.,Raposo, M. Manuela M.
, p. 163 - 169 (2015/03/30)
A series of novel photochromic cationic stilbenes dyes bearing different aromatic systems were easily synthesized from (hetero)aromatic aldehydes. The photoisomerization of the double bond can be achieved through irradiation with ultraviolet or visible light, for few seconds, leading to the Z isomers that return much faster to the initial state than common stilbenes. Benzothiazolium dyes with electron donating substituents exhibited very fast thermal back reactions (1 s). Pyrrole-benzothiazolium dye showed a higher lifetime of the Z isomer, in different solvents, including water (0.45-7.1 min). This cationic diarylethene can be switched between the E-Z states using visible light, in few minutes at room temperature, with a noticeable change in the visible spectrum.