159345-06-9Relevant articles and documents
Palladium-catalyzed suzuki-miyaura cross-coupling reactions of enantiomerically enriched potassium β-trifluoroboratoamides with various aryl- and hetaryl chlorides
Molander, Gary A.,Shin, Inji,Jean-Gerard, Ludivine
supporting information; experimental part, p. 4384 - 4387 (2010/12/24)
Figure Presented. Enantiomerically enriched potassium β- trifluoroboratoamides were synthesized as air-stable solids in greater than 95:5 dr using pseudoephedrine as the chiral auxiliary. With these chiral nucleophiles, Suzuki-Miyaura cross-coupling react
Syntheses of the C-1 alkyl side chains of Zaragozic acids A and C
Bach, Jordi,Galobardes, Marta,Garcia, Jordi,Romea, Pedro,Cristina, Tey,Urpi, Felix,Vilarrasa, Jaume
, p. 6765 - 6768 (2007/10/03)
Asymmetric syntheses of the C-1 alkyl side chains of Zaragozic acids A and C from a common chiral precursor 4 are reported. The stereoselective reduction of unsaturated ketones 8 and 10 is the key step of both syntheses.
Asymmetric synthesis of 1,3-dialkyl-substituted carbon chains of any stereochemical configuration by an iterable process
Myers, Andrew G.,Yang, Bryant H.,Chen, Hou,Kopecky, David J.
, p. 457 - 459 (2007/10/03)
A highly practical, iterable method for the preparation of 1,3,5,n(odd)-polyalkyl-substituted carbon chains based upon the asymmetric alkylation of pseudoephedrine amide enolates is described.