159694-94-7

Basic information

• Product Name: [(N(CH₂(C₇H₄N₂(CH₃)))3)ZnOCO(C₆H₄(OCOCH₃))]⁽¹⁺⁾*ClO₄^(1-) = [(N(CH₂(C₇H₄N₂(CH₃)))3)ZnOCO(C₆H₄(OCOCH₃))](ClO₄)
• CAS NO: 159694-94-7
• Molecular Weight: 793.551
• Mol File: 159694-94-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(N(CH₂(C₇H₄N₂(CH₃)))3)ZnOCO(C₆H₄(OCOCH₃))]⁽¹⁺⁾*ClO₄^(1-) = [(N(CH₂(C₇H₄N₂(CH₃)))3)ZnOCO(C₆H₄(OCOCH₃))](ClO₄)(CAS DataBase Reference)
• NIST Chemistry Reference: [(N(CH₂(C₇H₄N₂(CH₃)))3)ZnOCO(C₆H₄(OCOCH₃))]⁽¹⁺⁾*ClO₄^(1-) = [(N(CH₂(C₇H₄N₂(CH₃)))3)ZnOCO(C₆H₄(OCOCH₃))](ClO₄)(159694-94-7)
• EPA Substance Registry System: [(N(CH₂(C₇H₄N₂(CH₃)))3)ZnOCO(C₆H₄(OCOCH₃))]⁽¹⁺⁾*ClO₄^(1-) = [(N(CH₂(C₇H₄N₂(CH₃)))3)ZnOCO(C₆H₄(OCOCH₃))](ClO₄)(159694-94-7)

Safety Data

• Hazardous Substances Data: 159694-94-7(Hazardous Substances Data)

Upstream product

• 493-53-8 sodium O-acetylsalicylate 
• 82137-72-2 tris(N-methylbenzimidazol-2-ylmethyl)amine 

Relevant articles and documents

Functional Zinc Complexes of Tris(imidazolylmethyl)amine Ligands

The three N-R-substituted tris(benzimidazolylmethyl)amine ligands L (1a: R = H, 1b: R = Me, 1c: R = Bz) form zinc complexes with biologically active ligands of the fifth coordination site, starting from L, Zn(ClO4)2, and the coligand.The N-protected amino acids glycine, histidine, and cysteine yield ClO4 (2a, 3a, 4a).Aspirin, salicylic acid, and orotic acid are incorporated as ClO4 (5a-c: X = O-acetylsalicylate, 6a: X = salicylate, 7a-c: X = orotate).Similarly the sulfonamide furosemide is bound by its carboxylate function in ClO4 (8a-c).The aqua complex resulting from ligand 1a and Zn(ClO4)2 forms hydrogen bonds to nitriles and aldehydes, which has allowed the isolation of (ClO4)2 (9a: RCN = MeCN, 10a: RCN = PrCN) and of (ClO4)2 (11a: RCHO = anisaldehyde, 12a: RCHO = p-tolualdehyde).The structure determination of the salicylate complex 6a has confirmed the monodentate O-coordination of the carboxylate substrates to zinc. - Key Words: Zinc complexes / Encapsulating ligands / Bioligands / Structure