15971-63-8Relevant articles and documents
Copper(II)-catalyzed aerobic oxidation of hydrazides to Azo intermediates and their Diels-Alder versus ene trapping
Chaiyaveij, Duangduan,Whiting, Andrew
supporting information, (2021/12/01)
The oxidation of diethyl 1, 2-hydrazinedicarboxylate using a catalytic Cu(II)-oxazoline system occurs at RT in air, resulting in azo generation, which can then be trapped in situ via hetero-Diels-Alder (HDA) and competitive ene-reactions, with chemoselect
Electrosynthesis of cyclic α-carbonylazo compounds. Chemical stability of the electrogenerated dienophiles and in situ trapping of dienes
Lorans,Hurvois,Moinet
, p. 807 - 813 (2007/10/03)
Dienophilic cyclic α-carbonylazo compounds were prepared electrochemically by oxidation of the corresponding hydrazino compounds using a flow cell fitted with a graphite felt anode in acidic methanol or acetonitrile. The instability of these compounds in methanol was first studied. In situ Diels-Alder additions of these electrogenerated dienophiles and various dienes were performed in relatively good yields in acidic methanol or acetonitrile.
Anodic co-oxidation of urazole and ferrocenes: First trapping of cyclopentadienols
Lorans, Jocelyn,Pierre, Fabrice,Toupet, Loic,Moinet, Claude
, p. 1279 - 1280 (2007/10/03)
Cyclopentadien-5-ols, the major products resulting from decomposition of some ferrocenium cations by molecular oxygen, are regio- and stereo-selectively trapped by 4-phenyl-1,2,4-triazoline-3,5-dione.