159766-59-3

Basic information

• Product Name: N,N-diallyl-(2-bromophenyl)amine
• Synonyms: N,N-diallyl-(2-bromophenyl)amine
• CAS NO: 159766-59-3
• Molecular Weight: 252.154
• Mol File: 159766-59-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N,N-diallyl-(2-bromophenyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diallyl-(2-bromophenyl)amine(159766-59-3)
• EPA Substance Registry System: N,N-diallyl-(2-bromophenyl)amine(159766-59-3)

Safety Data

• Hazardous Substances Data: 159766-59-3(Hazardous Substances Data)

Upstream product

• 106-95-6 allyl bromide 
• 615-36-1 2-bromoaniline 

Downstream Products

• 176505-59-2 2-(1-Allyl-2,3-dihydro-1H-indol-3-yl)-1-(4-benzyloxy-3-methoxy-phenyl)-ethanol 
• 4375-15-9 3-methyl-2,3-dihydro-1H-indole 

Relevant articles and documents

Preparation of substituted indolines via anionic cyclization

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Highly selective N-allylation of anilines under microwave irradiation

An easy and rapid procedure for the preparation of a variety of mono- and bis-allylated anilines via the reaction of allyl bromide with a wide range of anilines under microwave irradiation is described. This approach allows use of mild conditions and short reaction times to give high selectivities and excellent yields.

Synthesis of polysubstituted indoles and indolines by means of zirconocene-stabilized benzyne complexes

The development of a new method for the regiospecific synthesis of polysubstituted indoles and indolines is reported. The key steps involve the generation of zirconocene-stabilized benzyne complexes and subsequent intramolecular olefin insertion reactions to provide tricyclic indoline zirconacycles. The zirconacyclic intermediates were cleaved with iodine to yield diiodo indolines, which were converted to a wide variety of indole and indoline products, such as analogs of tryptamine, serotonin, tryptophan, and the pharmacophore of CC-1065.