1598415-37-2

Basic information

• Product Name: (2R,3R,4R)-(E)-5-((tert-butyldimethylsilyl)oxy)pent-2-en-1-yl 3-hydroxy-4-((4-methoxybenzyl)oxy)-2,6-dimethylhept-6-enoate
• Synonyms: (2R,3R,4R)-(E)-5-((tert-butyldimethylsilyl)oxy)pent-2-en-1-yl 3-hydroxy-4-((4-methoxybenzyl)oxy)-2,6-dimethylhept-6-enoate
• CAS NO: 1598415-37-2
• Molecular Weight: 520.782
• Mol File: 1598415-37-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3R,4R)-(E)-5-((tert-butyldimethylsilyl)oxy)pent-2-en-1-yl 3-hydroxy-4-((4-methoxybenzyl)oxy)-2,6-dimethylhept-6-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4R)-(E)-5-((tert-butyldimethylsilyl)oxy)pent-2-en-1-yl 3-hydroxy-4-((4-methoxybenzyl)oxy)-2,6-dimethylhept-6-enoate(1598415-37-2)
• EPA Substance Registry System: (2R,3R,4R)-(E)-5-((tert-butyldimethylsilyl)oxy)pent-2-en-1-yl 3-hydroxy-4-((4-methoxybenzyl)oxy)-2,6-dimethylhept-6-enoate(1598415-37-2)

Safety Data

• Hazardous Substances Data: 1598415-37-2(Hazardous Substances Data)

Upstream product

• 1598415-36-1 (2R,3R,4R)-1-((R)-4-benzyl-2-thioxothiazolidin-3-yl)-3-hydroxy-4-((4-methoxybenzyl)oxy)-2,6-dimethylhept-6-en-1-one 
• 468745-31-5 (2E)-2-methyl-5-[((1,1-dimethyl)ethyl)dimethylsilyloxy]pent-2-en-1-ol 
• 1598415-35-0 (R)-2-((4-methoxybenzyl)oxy)-4-methylpent-4-enal 
• 1598415-34-9 (R)-2-((4-methoxybenzyl)oxy)-4-methylpent-4-en-1-ol 
• 1598415-33-8 C₂₀H₂₇NO₅ 

Relevant articles and documents

Stereoselective synthesis of quaternary carbons via the dianionic Ireland-Claisen rearrangement

A dianionic Ireland-Claisen rearrangement of chiral, nonracemic α-methyl-β-hydroxy allylic esters has been developed that proceeds with high diastereoselectivity and provides products containing three contiguous stereogenic carbons, including a quaternary center. The potential utility of the rearrangement for complex molecule synthesis is also demonstrated.