160158-78-1

Basic information

• Product Name: [Cp(PMe₃)2RuH₂]Cl
• CAS NO: 160158-78-1
• Molecular Weight: 355.79
• Mol File: 160158-78-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cp(PMe₃)2RuH₂]Cl(CAS DataBase Reference)
• NIST Chemistry Reference: [Cp(PMe₃)2RuH₂]Cl(160158-78-1)
• EPA Substance Registry System: [Cp(PMe₃)2RuH₂]Cl(160158-78-1)

Safety Data

• Hazardous Substances Data: 160158-78-1(Hazardous Substances Data)

Upstream product

• 90413-24-4 Cp(PMe₃)2RuH 
• 98-13-5 Phenyltrichlorosilane 

Relevant articles and documents

The chloride effect: Structural dependence of ruthenium silyl complexes on phosphorus and silicon substituents

The structures for a series of Cp(PR3)2RuSiX3 {PR3 = PMe3, SiX3 = SiCl3, SiMeCl2, SiPhCl2; PR3 = PMe2Ph, SiX3 = SiCl3} complexes were determined and compared. The Ru-Si and Si-Cl distances in these complexes increased when Cl was replaced with Me or Ph groups and correlated with the observed spectroscopic properties of these complexes. The structural variations were explained by d(Ru)-σ*(Si-Cl) π-back-bonding interactions.