1605-19-2Relevant articles and documents
Direct synthesis of 1,1-diarylalkenes from alkenyl phosphates via nickel(0)-catalysed Suzuki-Miyaura coupling
Hansen, Anders L.,Ebran, Jean-Philippe,Gogsig, Thomas M.,Skrydstrup, Troels
, p. 4137 - 4139 (2007/10/03)
A combination of Ni(COD)2 and PCy3 promotes effectively the Suzuki-Miyaura cross coupling of 1-arylalkenyl phosphates with aryl boronic acids with yields attaining 99%. The Royal Society of Chemistry 2006.
Multifunctional lithium containing initiator
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, (2008/06/13)
Highly desirable multifunctional lithium containing initiators are prepared by reacting a compound such as an organo lithium with an organic compound containing at least two 1,1-diphenylethylene groups. Such initiators can be prepared in the absence of polar solvents and are very desirable for the polymerization of dienes such as butadiene to a desirable 1,4 configuration. Several di-lithium compounds have been employed to initiate polymerization of various unsaturated organic monomers.