160594-72-9Relevant articles and documents
Facile synthesis of N,N-dialkylselenoamides from amides
Koketsu, Mamoru,Okayama, Yoshihiro,Aoki, Hiroshi,Ishihara, Hideharu
, p. 195 - 198 (2002)
The synthesis of the N,N-dialkylselenoamides from amides was discussed. These selenoamides were chlorinated with oxalyl chloride and then they were allowed to react with LiAlHSeH to afford the corresponding N,N-dialkylamides in moderate to good yields. Af
A Willgerodt-Kindler Type Selenation of Dihalomethane Derivatives, Chloroform, and Sodium Trichloroacetate by Treating with a Base, Elemental Selenium, and an Amine
Shimada, Kazuaki,Yamaguchi, Minoru,Sasaki, Tohru,Ohnishi, Kenji,Takikawa, Yuji
, p. 2235 - 2242 (2007/10/03)
Treatment of dihalomethane derivatives, chloroform, or sodium trichloroacetate with elemental selenium in the presence of NaH and an excess amount of an amine gave the corresponding selenoamides, selenoureas, and bis(selenocarbamoyl) triselenides in modest yields. These products were afforded from reactive intermediates related to "selenocarbonyl halides" and "selenophosgenoids" generated by the reaction of dichloromethanide ions and trichloromethanide ion with N-alkylated aminopolyselenide species (R2N-(Se)n-).