160648-26-0Relevant articles and documents
Pd salen complex@CPGO as a convenient, effective heterogeneous catalyst for Suzuki–Miyaura and Heck–Mizoroki cross-coupling reactions
Ghabdian, Mahdieh,Nasseri, Mohammad Ali,Allahresani, Ali,Motavallizadehkakhky, Alireza
, p. 1713 - 1728 (2018/05/25)
A Pd(II) Schiff base complex supported on graphene oxide nanosheets (Pd(II) salen@CPGO) has been synthesized and characterized by FT-IR, ICP-AES, XRD, SEM/EDX and TEM. The synthesized nanocatalyst has been found to be an efficient heterogeneous catalyst for Suzuki–Miyaura and Heck–Mizoroki coupling reactions. Pd(II) salen@CPGO could be separated and recovered easily from the reaction mixture and recycled several times without a discernible decrease in its catalytic activity. The construction of a solid sheet-supported Pd catalyst would be expected to be a promising system to perform heterogeneous catalytic reactions.
Silica-supported terpyridine palladium(II) complex as an efficient and reusable catalyst for Heck and Suzuki cross-coupling reactions
Amini, Mostafa M.,Feiz, Afsaneh,Dabiri, Minoo,Bazgir, Ayoob
, p. 86 - 90 (2014/02/14)
Silica-supported terpyridine palladium(II) was prepared and used as an effective and recyclable catalyst in Mizoroki-Heck and Suzuki-Miyaura coupling reactions. The catalyst was very effective for the Mizoroki-Heck reaction of aryl halides with olefins and conversion was in most cases excellent. The catalyst showed good thermal stability (up to 230 °C) and could be recovered and reused for four reaction cycles. The Suzuki coupling of aryl iodides with aryl boronic acids in the presence of the catalyst was also investigated and the reaction proceeded with a short reaction time and excellent conversion.