16075-82-4Relevant articles and documents
Bronsted acid catalyzed cycloisomerizations of 5,2-enyne-1-ones: Highly regioselective synthesis of 2,3-dihydro-4H-pyran-4-ones
Yang, Fang,Ji, Ke-Gong,Zhao, Shu-Chun,Ali, Shaukat,Ye, Yu-Ying,Liu, Xue-Yuan,Liang, Yong-Min
scheme or table, p. 6470 - 6474 (2012/06/15)
Dual-action catalyst: A Bronsted acid catalyzed regioselective cycloisomerization was found to be highly effective for the preparation of structurally diverse 2,3-dihydro-4H-pyran-4-ones in a 6-exo-trig manner from the corresponding 5,2-enyne-1-ones. In t
A New General Synthesis of 2,2-Dialkyl-2,3-dihydro-4H-pyran-4-ones and Their Application for the in situ Preparation of Electron-Rich Dienes in Carbonyl-Alkyne Exchange Reactions with Acetylenes
Obrecht, Daniel
, p. 27 - 46 (2007/10/02)
The substituted 2,2-dialkyl-2,3-dihydro-4H-pyran-4-ones of type II and III have been prepared by acid-catalyzed cyclization of the corresponding substituted acetylenic ketones I in good to excellent yields (Scheme 1).These 2,2-dialkyl-2,3-dihydro-4H-pyran