1608155-12-9

Basic information

• Product Name: N-(4-bromophenyl)-2-(7-bromo-9,9-diethylfluoren-2-yl)isoindole-1-carboxamide
• Synonyms: N-(4-bromophenyl)-2-(7-bromo-9,9-diethylfluoren-2-yl)isoindole-1-carboxamide
• CAS NO: 1608155-12-9
• Molecular Weight: 614.379
• Mol File: 1608155-12-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(4-bromophenyl)-2-(7-bromo-9,9-diethylfluoren-2-yl)isoindole-1-carboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-bromophenyl)-2-(7-bromo-9,9-diethylfluoren-2-yl)isoindole-1-carboxamide(1608155-12-9)
• EPA Substance Registry System: N-(4-bromophenyl)-2-(7-bromo-9,9-diethylfluoren-2-yl)isoindole-1-carboxamide(1608155-12-9)

Safety Data

• Hazardous Substances Data: 1608155-12-9(Hazardous Substances Data)

Upstream product

• 287493-15-6 2-bromo-9,9-diethyl-9H-fluorene 
• 1202709-54-3 7-bromo-9,9-diethyl-9H-fluoren-2-amine 
• 33554-73-3 1-bromo-4-isocyanobenzene 
• 643-79-8 o-phthalic dicarboxaldehyde 

Relevant articles and documents

Synthesis of fluorescent fluorene-isoindole-containing mono- and oligomers

Novel fluorene-isoindole-containing light-emitting mono- and oligomers were prepared. The synthesis of the monomers N-(4-bromo-phenyl)-2-(7-bromo-9,9- diethylfluoren-2-yl)-isoindole-1-carboxamide, N-(7-bromo-9,9-dibutylfluoren-2- yl)-2-(7-bromo-9,9-dibutylfluoren-2-yl)-isoindole-1-carboxamide, and N-[7-bromo-9,9-bis(2-ethylhexyl)-fluoren-2-yl]-2-[7-bromo-9,9-bis(2-ethylhexyl) -fluoren-2-yl]-isoindole -1-carboxamide was carried out by a three-component reaction of ortho-phthalaldehyde with the corresponding amine and isocyanide partners. The Ni(0) mediated polymerization reactions of the obtained monomers gave the corresponding mixture of oligomers from two up to twelve repeat units. The optical properties were also studied and it was found that the phenylene-containing oligomer emitted green light in dichloromethane solution, while both difluorene-containing oligomers, under the same conditions, proved to be blue light-emitters with good quantum efficiency.