160820-67-7Relevant articles and documents
Synthesis and Complex Chemistry of Functionalised Tripod Ligands RC(CH2PPh2)3
Janssen, Bernd C.,Sernau, Volker,Huttner, Gottfried,Asam, Alexander,Walter, Olaf,et al.
, p. 63 - 70 (2007/10/02)
Malonic ester 1 is alkylated and converted into the triols RC(CH2OH)3 (5).These are easily converted into the corresponding functionalised tripodal ligands RC(CH2PPh2)3 (7) with R = Bzl (a), n-C12H25 (b), (CH3)2CH(CH2)2 (c).Crystals suitable for X-ray crystallography have been obtained of the ligand 7a.In addition, the tripod ligands 7a and 7c have been further characterized by the syntheses and X-ray analyses of the nickel complex (8a), the iron complex (BF4)2 ; and the cobalt complex >(BPh4)(10*BF4). - Key Words: Tripod ligand synthesis / Tripod nickel chloro complexes / Tripod iron tris(acetonitrile) complexes / Tripod cobalt acetate complexes