16090-53-2

Basic information

• Product Name: 2,2,4,4,6,6-hexamethyl-1,3,5-trioxa-2,4,6-trigermacyclohexane
• Synonyms: 2,2,4,4,6,6-hexamethyl-1,3,5-trioxa-2,4,6-trigermacyclohexane
• CAS NO: 16090-53-2
• Molecular Weight: 355.977
• Mol File: 16090-53-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2,4,4,6,6-hexamethyl-1,3,5-trioxa-2,4,6-trigermacyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,4,4,6,6-hexamethyl-1,3,5-trioxa-2,4,6-trigermacyclohexane(16090-53-2)
• EPA Substance Registry System: 2,2,4,4,6,6-hexamethyl-1,3,5-trioxa-2,4,6-trigermacyclohexane(16090-53-2)

Safety Data

• Hazardous Substances Data: 16090-53-2(Hazardous Substances Data)

Upstream product

• 195721-62-1 1,1,2,2-tetramethyl-1,2-digerma-3,4,5,6-tetraphenylcyclohexa-3,5-diene 
• 670-54-2 ethenetetracarbonitrile 
• 3376-24-7 N-tert-butyl-α-phenylnitrone 
• 17394-49-9 nonamethyl cyclotrigermazane 
• 1137-96-8 N-(benzylidene)aniline N-oxide 
• 120658-04-0 dimethyl-1,1 thiagermetane-3,1 dioxide-3,3 
• 100-52-7 benzaldehyde 
• 21581-91-9 bis(chloromethyl)dimethylgermanium 

Relevant articles and documents

Ring contraction of 1,2-digermacyclohexa-3,5-dienes initiated by electron transfer reactions with TCNE

The thermal reaction of 1,2-digermacyclohexa-3,5-dienes with tetracyanoethylene (TCNE) gave 1-germacyclopenta-2,4-diene as a germylene extrusion compound through a charge-transfer complex. The 1-germacyclopenta-2,4-diene was trapped with TCNE to give 5,5,6,6-tetracyano-7-germanor-bornene.

Thermolyse, pyrolyse et photolyse d'heterocycles germanies et soufres a 4 et 5 chainons: especes intermediaires a germanium doublement lie

The thermolysis, pyrolysis and photolysis of thiagermetane , dithiagermolane and thiagermetane dioxide have been studied.Thiagermetane and dithiagermolane decompose leading to various new germylated heterocycles: , and probably proceed by two competitive mechanisms which involve the transient species germaethene , germathione , thiagermirane and thiadigermetane .Pyrolysis of thiagermetane dioxide also involves germaethene and probably a new doubly-bonded germanium species, the germasulfene (by mass spectroscopy), which finally gives germoxanes (Me2GeO)n (n = 3,4).