1609451-17-3

Basic information

• Product Name: (RuPhos)Pd(COC₂F₅)(OCOC₂F₅)
• CAS NO: 1609451-17-3
• Molecular Weight: 883.112
• Mol File: 1609451-17-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (RuPhos)Pd(COC₂F₅)(OCOC₂F₅)(CAS DataBase Reference)
• NIST Chemistry Reference: (RuPhos)Pd(COC₂F₅)(OCOC₂F₅)(1609451-17-3)
• EPA Substance Registry System: (RuPhos)Pd(COC₂F₅)(OCOC₂F₅)(1609451-17-3)

Safety Data

• Hazardous Substances Data: 1609451-17-3(Hazardous Substances Data)

Upstream product

• 787618-22-8 ruphos 

Downstream Products

• 1609451-24-2 (RuPhos)Pd(C₂F₅)(Ph) 
• 1609451-25-3 (RuPhos)Pd(C₂F₅)(o-C₆H₄CH₃) 
• 1609451-19-5 (RuPhos)Pd(C₂F₅)(OCOC₂F₅) 

Relevant articles and documents

Catalytic cycle for palladium-catalyzed decarbonylative trifluoromethylation using trifluoroacetic esters as the CF3 source

This paper demonstrates a catalytic cycle for Pd-catalyzed decarbonylative trifluoromethylation using trifluoroacetic esters as CF3 sources. The proposed cycle consists of four elementary steps: (1) oxidative addition of a trifluoroacetic ester to Pd0, (2) CO deinsertion from the resulting trifluoroacyl PdII complex, (3) transmetalation of a zinc aryl to PdII, and (4) aryl-CF3 bond-forming reductive elimination. The use of RuPhos as the supporting ligand enables each of these steps to proceed under mild conditions (3 sources.