160955-96-4

Basic information

• Product Name: Benzenesulfonamide, N-[(3-methoxyphenyl)methylene]-4-methyl-
• CAS NO: 160955-96-4
• Molecular Formula: C15H15NO3S
• Molecular Weight: 289.355
• Mol File: 160955-96-4.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-[(3-methoxyphenyl)methylene]-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-[(3-methoxyphenyl)methylene]-4-methyl-(160955-96-4)
• EPA Substance Registry System: Benzenesulfonamide, N-[(3-methoxyphenyl)methylene]-4-methyl-(160955-96-4)

Safety Data

• Hazardous Substances Data: 160955-96-4(Hazardous Substances Data)

Upstream product

• 127-65-1 chloroamine-T 
• 591-31-1 3-methoxy-benzaldehyde 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 70-55-3 toluene-4-sulfonamide 
• 672-78-6 methyl p-toluene sulfinate 
• 6873-55-8 p-tolylsulfinyl amide 
• 103-19-5 di(p-tolyl) disulfide 
• 871939-86-5 4-Methyl-benzenesulfinic acid 1-(3-methoxy-phenyl)-meth-(E)-ylideneamide 
• 6971-51-3 3-methoxybenzyl alcohol 

Downstream Products

• 1020398-78-0 bis(4-methoxyphenyl)(3-methoxyphenyl)methane 
• 1417742-38-1 (S)-N-[1-(3-methoxyphenyl)-2-methylene-3-oxobutyl]-4-methylbenzenesulfonamide 
• 1152292-52-8 (R)-N-[1-(3-methoxyphenyl)-2-methylene-3-oxobutyl]-4-methylbenzenesulfonamide 
• 1403506-80-8 N-[(1S)-2-cyano-1-(3-methoxyphenyl)propen-3-yl]-4-methylbenzenesulfonamide 

Relevant articles and documents

The diastereoselective synthesis of 2,3-diaryl-3-cyano-substituted pyrrolidines via the MgI2 mediated ring expansion of aryl cyclopropyl nitriles

The MgI2 mediated reaction of aryl substituted cyclopropyl nitriles with tosyl aldimines to give 2,3-diaryl-3-cyano-substituted pyrrolidines has been demonstrated. In all cases, the trans-diastereoisomer was determined to be the major product.

Alkenyl Exchange of Allylamines via Nickel(0)-Catalyzed C-C Bond Cleavage

A functional group exchange reaction between allylamines and alkenes via nickel-catalyzed C - C bond cleavage and formation was developed. This reaction provides a novel protocol, which does not require the use of unstable imine substrates, for the synthesis of allylamines, which are widely used in the production of fine chemicals, pharmaceuticals, and agrochemicals.

Formation of: N -sulfonyl imines from iminoiodinanes by iodine-promoted, N-centered radical sulfonamidation of aldehydes

A mild and operationally convenient formation of synthetically valuable N-sulfonyl imines from a range of aryl aldehydes by reaction with iminoiodinanes (PhINZ) and I2 has been developed. According to mechanistic experiments described within, the reaction is speculated to proceed through an unconventional light-promoted, N-centered radical (NCR) pathway involving a N,N-diiodosulfonamide reactive species. This method not only provides a new pathway toward the production of activated imines, but also serves as an example of a non-traditional means of carbonyl activation via an NCR species.