1609941-99-2Relevant articles and documents
A radical thia-Brook rearrangement
Quiclet-Sire, Béatrice,Zard, Samir Z.
, p. 5990 - 5992 (2014)
Geminal mercapto trialkyl- and trialkoxy-silanes undergo an efficient radical chain rearrangement, whereby the silyl group migrates from carbon to sulfur; the starting materials are readily obtained by exploiting the peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkyl- or trialkoxy-vinylsilanes. the Partner Organisations 2014.