1610372-19-4Relevant articles and documents
Nickel-catalyzed redox-economical coupling of alcohols and alkynes to form allylic alcohols
Nakai, Kenichiro,Yoshida, Yuji,Kurahashi, Takuya,Matsubara, Seijiro
supporting information, p. 7797 - 7800 (2014/06/23)
We have developed a redox-economical coupling reaction of alcohols and alkynes to form allylic alcohols under mild conditions. The reaction is redox-neutral as well as redox-economical and thus free from any additives such as a reductant or an oxidant. This atom-economical coupling can be applied for the conversion of both aliphatic and benzylic alcohols to the corresponding substituted allylic alcohols in a single synthetic operation.