161299-90-7Relevant articles and documents
Insights into the triple self-condensation reaction of thiophene-based methyl ketones and related compounds
Andicsová-Eckstein, Anita,Végh, Daniel,Kruto?íková, Al?beta,Tokárová, Zita
, p. 124 - 139 (2018/06/29)
The acid catalysed triple self-condensation of 1-thien-2-ylethanone (2-acetylthiophene) and five related compounds is presented. Tetrachlorosilane used as the Lewis acid produces dry hydrogen chloride which catalyzes the self-condensation process. Depending on the reaction conditions and the substitution of the carbonyl substrates, the reaction can proceed as a [2+2+2] cyclotrimerization towards C3-symmetric 1,3,5-trisubstituted benzenes, or as the single-type aldol condensation leading to 1,3-disubstituted (E)-β-methylchalcones. This is important for the design of new aromatic/olefinic compounds beyond the model structures. Synthesis of 4′-fluoro-3,5-di-(2-thienyl)biphenyl through a mixed-type aldol reaction using erbium triflate is discussed. Mechanistic rationale is provided.
Indoline compound and application thereof
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, (2018/04/28)
The invention discloses an indoline compound which has a structure as shown in formula (I), wherein in the formula (I), R1 is C1-C12 alkyl or C1-C12 alkoxy or C4-C20 heterocyclic radical, and heteroatom of the heterocyclic radical is N, S or O; and R2 is
Synthesis and Electrochromic Properties of Star-Shaped Oligomers with Phenyl Cores
Zeng, Jinming,Zhang, Xiaoyuan,Zhu, Xiaoting,Liu, Ping
, p. 2202 - 2206 (2017/09/11)
A series of star-shaped conjugated oligomers, 1,3,5-tri(2′-thienyl) benzene (3TB), 1,3,5-tri(3′,4′-ethylenedioxythienyl) benzene (3EB), 1,3,5-tri[5′,2“-(3”,4“-ethylenedioxy-thienyl)-2′-thienyl] benzene (3ETB), and 1,3,5-tri[5′,2”-(3“,4”-ethylenedioxy-thie