1613-96-3

Basic information

• Product Name: Benzenamine, N-[(4-methoxyphenyl)methylene]-, (E)-
• CAS NO: 1613-96-3
• Molecular Formula: C14H13NO
• Molecular Weight: 211.263
• Mol File: 1613-96-3.mol
• Article Data: 50

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-[(4-methoxyphenyl)methylene]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-[(4-methoxyphenyl)methylene]-, (E)-(1613-96-3)
• EPA Substance Registry System: Benzenamine, N-[(4-methoxyphenyl)methylene]-, (E)-(1613-96-3)

Safety Data

• Hazardous Substances Data: 1613-96-3(Hazardous Substances Data)

Usage

Description

Benzenamine, N-[(4-methoxyphenyl)methylene]-, (E)-, also known as N-(4-methoxybenzylidene)aniline, is an organic compound with the molecular formula C14H13NO. It exhibits a bright yellow to orange color and is widely used in the synthesis of dyes, pigments, polymers, and pharmaceuticals. The (E)configuration in its name signifies a trans double bond, which influences its chemical properties and reactivity.

Uses

Used in Dye and Pigment Industry:
Benzenamine, N-[(4-methoxyphenyl)methylene]-, (E)is used as a key intermediate in the synthesis of various dyes and pigments, providing vibrant colors and enhancing the stability of these compounds.
Used in Polymer Production:
Benzenamine, N-[(4-methoxyphenyl)methylene]-, (E)is utilized in the production of polymers, contributing to the development of materials with improved properties and performance.
Used in Pharmaceutical Manufacturing:
Benzenamine, N-[(4-methoxyphenyl)methylene]-, (E)serves as an intermediate in the manufacturing of pharmaceuticals, playing a crucial role in the synthesis of various medicinal compounds.
Used in Organic Synthesis:
It is employed in organic synthesis as a reactant in chemical reactions, enabling the creation of a wide range of other compounds for various applications.

Upstream product

• 62-53-3 aniline 
• 105-13-5 4-Methoxybenzyl alcohol 
• 2393-23-9 4-methoxy-benzylamine 
• 1750-36-3 (E)-N-benzylidenebenzenamine 
• 98-95-3 nitrobenzene 
• 3526-43-0 N-(4-methoxybenzyl)aniline 
• 83871-65-2 1,2-Dianilino-1,2-di(p-methoxyphenyl)ethan 
• 3585-93-1 p-methoxydiphenylnitrone 
• 123-11-5 4-methoxy-benzaldehyde 

Downstream Products

• 123-11-5 4-methoxy-benzaldehyde 
• 1638645-85-8 3-(6,8-dimethoxy-1-(4-methoxyphenyl)-2-phenyl-1,2-dihydroisoquinolin-3-yl)oxazolidin-2-one 
• 1041777-96-1 (E,E)-3,6-bis[2-(4-methoxyphenyl)vinyl]pyridazine 
• 244179-16-6 3,6-bis(4-hydroxynhenyl)phthalic anhydride 
• 244179-15-5 3,6-bis(4-methoxyphenyl)phthalic anhydride 
• 244179-14-4 4,7-bis-(4-methoxy-phenyl)-3a,4,7,7a-tetrahydro-isobenzofuran-1,3-dione 
• 244179-17-7 3,6-bis(4-methoxyphenyl)-4,5-dicyanohexane 
• 503812-15-5 ethyl, 2-diazo-4,4-difluoro-5-(4-methoxyphenyl)-3-oxo-5-phenylamino-pentanoate 

Relevant articles and documents

Effects of molecular conformation on the spectroscopic properties of 4,4′-disubstituted benzylideneanilines

The relationship between the molecular conformation and spectroscopic properties of unsymmetrical 4,4′-disubstituted benzylideneanilines, was explored by the combination of experiment and reference data. Crystal structure information and spectroscopic beh

Cooperative catalysis of molybdenum with organocatalysts for distribution of products between amines and imines

Multi-amino groups and nitrogen donors compound was discovered as an organocatalyst for N-alkylation of alcohols with amines in the presence of Mo(CO)6. The Mo(CO)6/organocatalyst binary system has shown to be a highly active catalyst for the N-alkylation reaction between alcohols and amines with excellent tolerance of variable starting materials bearing different functional groups. Of particular note, this method possessing a superiority selectivity in the synthesis of N-alkylated amines or imines, which can be controlled by the reaction temperature. The cooperative catalysis mechanism in combination of Mo(CO)6 with organocatalyst was elucidated by control experiments.

A Highly Selective Manganese-Catalyzed Synthesis of Imines under Phosphine-Free Conditions

An efficient and highly selective phosphine-free NN-manganese(I) complex catalyst system was developed for the acceptorless dehydrogenative coupling of alcohols with amines to form imines. The coupling reactions underwent at 3 mol % catalyst loading, and a large range of alcohols and amines with diverse functional groups was applied, including challenging diol and diamine. The target imine products were obtained in good to excellent yields. The present work provides an alternative method to construct highly active nonprecious metal complex catalysts based on phosphine-free ligands.