1613507-22-4

Basic information

• Product Name: (S,E)-1-chloro-4-(4-(4-methoxyphenyl)but-3-en-2-yl)benzene
• Synonyms: (S,E)-1-chloro-4-(4-(4-methoxyphenyl)but-3-en-2-yl)benzene
• CAS NO: 1613507-22-4
• Molecular Weight: 272.774
• Mol File: 1613507-22-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S,E)-1-chloro-4-(4-(4-methoxyphenyl)but-3-en-2-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (S,E)-1-chloro-4-(4-(4-methoxyphenyl)but-3-en-2-yl)benzene(1613507-22-4)
• EPA Substance Registry System: (S,E)-1-chloro-4-(4-(4-methoxyphenyl)but-3-en-2-yl)benzene(1613507-22-4)

Safety Data

• Hazardous Substances Data: 1613507-22-4(Hazardous Substances Data)

Upstream product

• 20001-65-4 1-chloro-4-(1-chloroethyl)benzene 
• 6303-59-9 (E)-4-(2-bromo-vinyl)-anisole 
• 3391-10-4 1-(p-chlorophenyl)ethyl alcohol 
• 174174-00-6 (+)-(2R,3E)-4-(4'-methoxyphenyl)but-3-en-2-ol 
• 7519-91-7 tris(4-chlorophenyl)boroxine 
• 3815-30-3 4-(4-methoxyphenyl)-3-buten-2-one 

Relevant articles and documents

Nickel-catalyzed asymmetric reductive cross-coupling between vinyl and benzyl electrophiles

A Ni-catalyzed asymmetric reductive cross-coupling between vinyl bromides and benzyl chlorides has been developed. This method provides direct access to enantioenriched products bearing aryl-substituted tertiary allylic stereogenic centers from simple, stable starting materials. A broad substrate scope is achieved under mild reaction conditions that preclude the pregeneration of organometallic reagents and the regioselectivity issues commonly associated with asymmetric allylic arylation.