16155-32-1

Basic information

• Product Name: Benzene, 1-chloro-4-(propylthio)-
• Synonyms: 1-chloro-4-propylthiobenzene;p-chlorophenyl propyl sulfide;Propyl-(4-chlorphenyl)-sulfid
• CAS NO: 16155-32-1
• Molecular Formula: C9H11ClS
• Molecular Weight: 186.705
• Mol File: 16155-32-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-4-(propylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-4-(propylthio)-(16155-32-1)
• EPA Substance Registry System: Benzene, 1-chloro-4-(propylthio)-(16155-32-1)

Safety Data

• Hazardous Substances Data: 16155-32-1(Hazardous Substances Data)

Upstream product

• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 2315-68-6 propyl benzoate 
• 106-94-5 propyl bromide 
• 106-54-7 p-Chlorothiophenol 
• 14366-66-6 1-chloro-4-[(3-chloropropyl)thio]benzene 

Downstream Products

• 1027158-94-6 1-[1-(4-Chloro-phenylsulfanyl)-propoxy]-2,4-diethyl-benzene 
• 1027837-04-2 C₁₆H₁₇ClOS 
• 935662-12-7 (S_S)-p-chlorophenyl propyl sulfoxide 
• 817562-59-7 1,1,2-trifluoro-2-(p-chlorophenylthio)propane 
• 935662-17-2 (S,S_S)-p-chlorophenyl 1-chloropropyl sulfoxide 
• 144265-57-6 1-Chloro-4-(1-chloro-propylsulfanyl)-benzene 
• 101167-08-2 4-chlorophenyl propyl sulfone 
• 21865-08-7 p-Chlorphenylpropylsulfoxid 

Relevant articles and documents

Production of Alkyl Aryl Sulfides from Aromatic Disulfides and Alkyl Carboxylates via a Disilathiane–Disulfide Interchange Reaction

The results of this study show that disilathiane is an effective mediator in the synthesis of alkyl aryl sulfides with disulfides and alkyl carboxylates. Mechanistic studies suggest that disilathiane promotes cleavage of the sulfur–sulfur bond of disulfides to generate thiosilane as a key intermediate. Diselenides were also applicable to this transformation to produce the corresponding selenides.

One-pot synthesis of sulfides by reaction of disulfides with alkyl halides in the presence of sodium dithionite

Sodium dithionite-promoted synthesis of unsymmetrical diorganyl sulfides by a reaction of diaryl disulfides with alkyl halides at r.t. has been developed. The advantages offered by this method are operational simplicity, a faster reaction, neutral and mild reaction conditions, and moderate to good yields of products.

Selective trifluorination of alkyl aryl sulfides using IF5

In the reaction of IF5 with alkyl aryl sulfides in heptane under reflux conditions, the arylthio group migrated once and three fluorine atoms were selectively introduced on the alkyl chain. In order to find the reason why the reaction stopped at the trifluorination step, we examined the oxidation potentials of the starting material, a reaction intermediate, and the product, and the time course of the reactions. Graphical Abstract.