161555-31-3

Basic information

• Product Name: (6R,9S)-1-aza-3-amino-4-benzyl-9-<(tert-butyldimethylsiloxy)methyl>-2-oxobicyclo<4.3.0>non-3-ene
• Synonyms: (6R,9S)-1-aza-3-amino-4-benzyl-9-<(tert-butyldimethylsiloxy)methyl>-2-oxobicyclo<4.3.0>non-3-ene
• CAS NO: 161555-31-3
• Molecular Weight: 386.61
• Mol File: 161555-31-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (6R,9S)-1-aza-3-amino-4-benzyl-9-<(tert-butyldimethylsiloxy)methyl>-2-oxobicyclo<4.3.0>non-3-ene(CAS DataBase Reference)
• NIST Chemistry Reference: (6R,9S)-1-aza-3-amino-4-benzyl-9-<(tert-butyldimethylsiloxy)methyl>-2-oxobicyclo<4.3.0>non-3-ene(161555-31-3)
• EPA Substance Registry System: (6R,9S)-1-aza-3-amino-4-benzyl-9-<(tert-butyldimethylsiloxy)methyl>-2-oxobicyclo<4.3.0>non-3-ene(161555-31-3)

Safety Data

• Hazardous Substances Data: 161555-31-3(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 23356-96-9 (S)-1-Pyrrolidin-2-yl-methanol 

Downstream Products

• 173395-77-2 (6R,9S)-1-aza-4-benzyl-3-<amino>-9-(hydroxymethyl)-2-oxobicyclo<4.3.0>non-3-ene 
• 173395-78-3 (6R,9S)-1-aza-4-benzyl-3-<amino>-9-carboxy-2-oxobicyclo<4.3.0>non-3-ene 
• 161555-32-4 (6R,9S,12S)-1-aza-3-(pyroglutamylamino)-4-benzyl-9-<<(tert-butyldimethylsilyl)oxy>methyl>-2-oxobicyclo<4.3.0>nonene 

Relevant articles and documents

The use of HMQC-TOCSY experiments for elucidating the structures of bicyclic lactams: Uncovering a surprise rearrangement in the synthesis of a key prophe building block

HMQC-TOCSY experiments were used to unequivocally assign the ring skeletons of several bicyclic lactams. This work demonstrated the power of these techniques for establishing the complete carbon connectivity of peptide building blocks with closely overlap