161584-76-5

Basic information

• Product Name: Bis(1-oxo-2-pyridyl)methoxy<4-((tert-butyldimethylsilyl)oxy)phenyl>methane
• Synonyms: Bis(1-oxo-2-pyridyl)methoxy<4-((tert-butyldimethylsilyl)oxy)phenyl>methane
• CAS NO: 161584-76-5
• Molecular Weight: 438.599
• Mol File: 161584-76-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Bis(1-oxo-2-pyridyl)methoxy<4-((tert-butyldimethylsilyl)oxy)phenyl>methane(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(1-oxo-2-pyridyl)methoxy<4-((tert-butyldimethylsilyl)oxy)phenyl>methane(161584-76-5)
• EPA Substance Registry System: Bis(1-oxo-2-pyridyl)methoxy<4-((tert-butyldimethylsilyl)oxy)phenyl>methane(161584-76-5)

Safety Data

• Hazardous Substances Data: 161584-76-5(Hazardous Substances Data)

Upstream product

• 161584-82-3 Di(2-pyridyl)methoxy<4-((tert-butyldimethylsilyl)oxy)phenyl>methane 

Downstream Products

• 49669-22-9 6,6'-Dibromo-2,2'-bipyridine 
• 161584-87-8 Bis(6-bromo-2-pyridyl)<4-((tert-butyldimethylsilyl)oxy)phenyl>methanol 

Relevant articles and documents

Preparation of Dipyridylmethane Ligands with Pseudo-C2 Symmetry. Grafting on Polystyrenes via Transformation to Phenolic Derivatives

Efficient grafting of dipyridylmethane ligands on highly cross-linked as well as gel-type chloromethylated polystyrenes has been achieved using phenolic derivatives of the ligands.In this way, chiral polymer-supported ligands with pseudo-C2 symmetry were obtained.The synthesis of the ligands and their grafting under mild conditions are described, as well as the preparation of monomeric models.During reduction of 6,6'-(2,2-dimethyl-1-oxopropyl) derivatives with sodium borohydride, the R,S isomers were unexpectedly formed with high selectivity.