1616-50-8Relevant articles and documents
Synthesis of rhodium(III)-catalyzed isoquinoline derivatives from allyl carbonates and benzimidates with hydrogen evolution
Dong, Lin,Li, Chao,Liu, Man,Xu, Hui-Bei,Zhang, Jing
, p. 1412 - 1416 (2020)
A novel Rh(iii)-catalyzed cascade C-H activation/cyclization approach to access isoquinoline derivatives from benzimidates and available allyl carbonates with the liberation of H2 has been realized. Allyl carbonates were first used as a versati
Light/Palladium-Promoted Benzylic C?H Acylation Using a Benzoyl Group as the Photo-Directing Group
Masuda, Yusuke,Ishida, Naoki,Murakami, Masahiro
supporting information, p. 403 - 406 (2019/01/22)
2-Methylphenyl ketones undergo site-selective acylation at the benzylic position when treated with acid anhydride under UV irradiation in the presence of a palladium catalyst. The benzoyl carbonyl group serves as the photo-directing group so that the ortho benzylic C?H bond is activated site-selectively.
Rh-catalyzed sequential oxidative C-H activation/annulation with geminal-substituted vinyl acetates to access isoquinolines
Chu, Haoke,Sun, Song,Yu, Jin-Tao,Cheng, Jiang
supporting information, p. 13327 - 13329 (2015/08/24)
The concise synthesis of 3-substituted or non-C3-substituted isoquinolines through Rh-catalyzed sequential oxidative C-H activation/annulation with geminal-substituted vinyl acetates was developed with good functional group tolerance. The protocol was successfully applied to the total synthesis of the natural product papaverine.
