16174-24-6Relevant articles and documents
Synthesis of dibenzo[: A, d] cycloheptanoids via aryne insertion into 2-arylidene-1,3-indandiones
Payili, Nagaraju,Rekula, Santhosh Reddy,Aitha, Anjaiah,Mutha, V.V.S.R.N. Anji Karun,Gangu Naidu, Challa,Yennam, Satyanarayana
, p. 9442 - 9446 (2019)
A novel and unexpected aryne insertion cascade reaction on 2-arylidene-1,3-indandiones via conjugate addition of fluoride followed by formal C-C insertion is developed to afford dibenzo[a,d]cycloheptanoid derivatives in good yields with a single isomer. T
Syntheses and Reactions of Spiroanthronetriazolines
Hirakawa, Kiyoichi,Ito, Tsutomu,Okubo, Yoshiji,Nakazawa, Sho
, p. 1668 - 1672 (2007/10/02)
Quinone methide 1a reacts with aryl azides 2 to give the corresponding spiroanthronetriazolines 3 along with byproducts, collected in Table I, which are formed by the thermal reaction of 3 or 1a.Quinone methide 1b adds to azides 2 to give spiroanthronetriazolines 5 or their subsequent products.Pyrolysis of 3 regenerates the starting quinone methide 1a and azide 2, and their photolysis leads to 1a.Pyrolysis and photolysis of 5 yield aryliminoanthrone 7, arylaminodibenzocycloheptenone 12, or its isomer 19.Attempts to convert 3 and 5 into spiroanthroneaziridines 14 and 15, respectively, were unsuccessful.Reactions of 3 and 5 with acid catalysts give the rearrangement products dibenzocycloheptenediones 23 and 24, respectively, in high yields.These reactions are discussed in mechanistic terms.
