161742-12-7Relevant articles and documents
Palladium-catalyzed chemoselective intramolecular cyclization of 2-bromoaryl alkenenitriles
Deng, Jui-Hui,Tai, Huo-Mu,Yang, Chau-Chen
, p. 327 - 341 (2007/10/03)
The chemoselectivity in the palladium-catalyzed intramolecular cyclization of 2-(o-bromoaryl)alkenenitriles depends on the nature of α-substitutents. 2-(o-Bromoanilino)alkenenitriles attacked the cyano group, followed by the cyano group transposition and
Palladium-catalysed Regioselective Cyclisation of Unsaturated Bromoanilinoalkenenitriles
Yang, Chau-Chen,Sun, Pei-Jiun,Fang, Jim-Min
, p. 2629 - 2630 (2007/10/02)
α-(o-Bromoanilino)alkenenitriles are converted to 2-(methylamino)benzonitrile and varied γ-carbolines by catalysis with palladium; the reactions may involve intramolecular aryl additions to the cyano group and other processes such as cyano group transposi