1618098-60-4Relevant articles and documents
Total synthesis of (-)-crinipellin A
Kang, Taek,Song, Seog Boem,Kim, Won-Yeob,Kim, Byung Gyu,Lee, Hee-Yoon
, p. 10274 - 10276 (2014)
The first total synthesis of (-)-crinipellin A is described. The tetraquinane core skeleton of crinipellin A was assembled through the tandem [2 + 3] cycloaddition reaction of an allenyl diazo substrate containing a cyclopentane ring in a single operation. The absolute stereochemistry was confirmed through the total synthesis.