16192-08-8

Basic information

• Product Name: 1-methyl-4-(1,2-propadienylsulfonyl)benzene
• Synonyms: 1-methyl-4-(1,2-propadienylsulfonyl)benzene
• CAS NO: 16192-08-8
• Molecular Formula: C₁₀H₁₀O₂S
• Molecular Weight: 194.2502
• Mol File: 16192-08-8.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 357.3°C at 760 mmHg
• Flash Point: 211.4°C
• Appearance: /
• Density: 1.114g/cm³
• Vapor Pressure: 5.67E-05mmHg at 25°C
• Refractive Index: 1.53
• CAS DataBase Reference: 1-methyl-4-(1,2-propadienylsulfonyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-4-(1,2-propadienylsulfonyl)benzene(16192-08-8)
• EPA Substance Registry System: 1-methyl-4-(1,2-propadienylsulfonyl)benzene(16192-08-8)

Safety Data

• Hazardous Substances Data: 16192-08-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H10O2S/c1-3-8-13(11,12)10-6-4-9(2)5-7-10/h4-8H,1H2,2H3

Upstream product

• 16192-07-7 4-tosylacetonitrile 
• 14790-33-1 prop-2-yn-1-yl 4-methylbenzenesulfinate 
• 112389-74-9 1-Methyl-4-(2-phenylselanyl-prop-2-ene-1-sulfonyl)-benzene 
• 98-59-9 p-toluenesulfonyl chloride 
• 168064-80-0 (Z)-2-phenylseleno-1-(p-toluenesulfonyl)-1-propene 
• 10439-23-3 4-methylbenzenesulfinyl chloride 
• 68819-94-3 p-tolyl benzeneselenosulfonate 
• 112389-72-7 1-((E)-3-Chloro-2-phenylselanyl-prop-1-ene-1-sulfonyl)-4-methyl-benzene 
• 112389-71-6 1-Methyl-4-((E)-2-phenylselanyl-prop-1-ene-1-sulfonyl)-benzene 
• 33597-89-6 4-methylphenyl prop-2'-ynyl sulfide 
• 10486-08-5 sodium p-thiocresolate 
• 624-65-7 2-propynyl chloride 
• 42091-60-1 1-tolyl-p-sulphinylpropa-1,2-diene 
• 106-45-6 para-thiocresol 

Downstream Products

• 70411-70-0 1-Methyl-4-(2-methylene-hexane-1-sulfonyl)-benzene 
• 42104-32-5 1-Methyl-4-(3-methyl-2-methylene-butane-1-sulfonyl)-benzene 
• 16192-04-4 1-methyl-4-(2-methylallylsulfonyl)benzene 
• 70411-71-1 1-(3,3-Dimethyl-2-methylene-butane-1-sulfonyl)-4-methyl-benzene 
• 19523-28-5 1-methyl-4-(2-phenyl-2-prop-2-ene-1-sulfonyl)-benzene 
• 58093-16-6 4-Methyl-3-(toluene-4-sulfonyl)-pent-4-en-2-one 
• 544418-06-6 1-(3-tert-butoxy-cyclobutylidenemethanesulfonyl)-4-methyl-benzene 
• 1058856-80-6 C₁₀H₁₁O₂S^(1-) 
• 1616135-56-8 dimethyl(phenyl)(3-tosylprop-1-en-2-yl)silane 
• 1233250-61-7 (3S,3aR,6aS,SS)-3-ethoxy-6a[(4-methylphenyl)sulfinyl]-5-[(4-methylphenyl)sulfonyl]-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one 
• 35925-44-1 4,4′-(prop-2-ene-1,2-diyldisulfonyl)bis(methylbenzene) 

Relevant articles and documents

Metal-Free C-C Coupling of an Allenyl Sulfone with Picolyl Amides to Access Vinyl Sulfones via Pyridine-Initiated in Situ Generation of Sulfinate Anion

Vinyl sulfones are privileged motifs known for their biological activity and synthetic utility. Synthetic transformations to efficiently access high-value compounds with these motifs are desired and sought after. Herein, a new procedure is described to fo

Efficient synthesis of aliphatic sulfones by Mg mediated coupling reactions of sulfonyl chlorides and aliphatic halides

Sulfonyl chlorides were reduced to anhydrous sulfinate salts with magnesium under sonication. These sulfinates were alkylated to sulfones with alkyl chlorides in the presence of catalytic sodium iodide under sonication. A variety of aliphatic sulfones was efficiently prepared by this one-pot two-step procedure.

Additions of Organocopper Reagents and Heteroatom Nucleophiles to l-Phenylseleno-2-(p-toluenesulfonyl)ethyne. Preparation of Vinyl and Allenic Sulfones and Formation of Michael, Anti-Michael, and Rearrangement Products

l-Phenylseleno-2-(p-toluenesulfonyl)ethyne (4) was produced nearly quantitatively from p-(toluenesulfonyl)ethyne and benzeneselenenyl chloride. It undenvent stereo- and regioselective synadditions of organocopper reagents RCu(CN)Li to the β-position of th