1619998-85-4

Basic information

• Product Name: (E)-methyl 2-methylene-5-phenylpent-4-enoate
• Synonyms: (E)-methyl 2-methylene-5-phenylpent-4-enoate
• CAS NO: 1619998-85-4
• Molecular Weight: 202.253
• Mol File: 1619998-85-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-methyl 2-methylene-5-phenylpent-4-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-methyl 2-methylene-5-phenylpent-4-enoate(1619998-85-4)
• EPA Substance Registry System: (E)-methyl 2-methylene-5-phenylpent-4-enoate(1619998-85-4)

Safety Data

• Hazardous Substances Data: 1619998-85-4(Hazardous Substances Data)

Upstream product

• 2689-68-1 methyl 4-oxotetrahydrothiophene-3-carboxylate 
• 14371-10-9 (E)-3-phenylpropenal 
• 67-56-1 methanol 
• 72651-96-8 (E)-2,2-dimethyl-5-(3-phenylallyl)-1,3-dioxane-4,6-dione 
• 33797-51-2 eschenmoser's salt 

Relevant articles and documents

Sequential Palladium-Catalyzed Allylic Alkylation/retro-Dieckmann Fragmentation Strategy for the Synthesis of α-Substituted Acrylonitriles

A straightforward synthesis of α-substituted acrylonitriles is described using 4-cyano-3-oxotetrahydro-thiophene (c-THT) as an acrylonitrile surrogate. This unprecedented two-step sequence featuring a palladium-catalyzed allylic alkylation (Pd-AA) and a retro-Dieckmann fragmentation provides a general entry into diversely substituted 1,4-dienes.